Monday 5 January 2015

A PdCl2-Based Hydrogenation Catalyst for Glass Microreactors

A PdCl2-Based Hydrogenation Catalyst for Glass Microreactors

JournalJournal of Flow Chemistry
PublisherAkadémiai Kiadó
ISSN2062-249X (Print)
2063-0212 (Online)
SubjectFlow Chemistry
IssueVolume 4, Number 3/September 2014
Pages110-112
DOI10.1556/JFC-D-13-00036
Clemens R. Horn1 Email for hornc@corning.com, Carine Cerato-Noyerie
17bis avenue de Valvins Corning European Technology Center F- 77210 Avon France
hornc@corning.com

Abstract

A convenient and simple PdCl2-based hydrogenation catalyst has been developed. The liquid, air, and moisture stable precursor is pumped into the reactor where it is temporarily immobilized and reduced on the channel surface into Pd(0), providing a constant high activity for hydrogenation reaction. The catalyst is leached with time, avoiding any kind of clogging problems during long time runs.


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